If there is a line that goes all the way around the sides, then yes that is very suspicious and I'd be making sure it hasn't been hollowed, filled and silver soldered up.
Jewelers have the knowledge and tooling to do this very easily. That said, XRF and PMV will not penetrate to the core of a bar, 2mm max. So first I would try what Chip said and use a magnet, rare earth type if possible, plus weigh it and see how close to 311 grams it is (10oz bar?). The core would of unlikely been filled with a ferrous metal though (assuming it has been cored and done by a jeweler), more like lead, so a magnet will not pick that up. So failing the magnet test, if you do have access to an XRF or PMV, test the material along the line. Jewelers silver solder cannot be pure silver, its usually only majority silver, max Stirling level. So if there is discrepancy in purity along that line, at this point you should try your best to return and refund it to where you got it, saying it's dodgy AF. Failing that, I would shear it in half with big bolt cutters, if it really has been hollowed, reference consumer law and demand a refund. If you bought privately, and cannot contact, then try sell the silver that's there for melt value to salvage what you can.
If you know anyone in the NDT industry, it could also be ultrasonically tested without destroying it, which will test 100% the way through it for any faults at all. There is also spec grav test too.
If the marks don't go all the way around, then they might be just vault scuff marks. But for everyone, you should check your bars for these types of marks as guaranteed some jewelers do this to get a free supply of silver.