A collector bought a gold bar in 2010 and found there were rusts and red spots on the appearance in 2012. what cause the oxidation. http://en.shyzgw.com/New.asp?id=2076
Gold and iron don't mix into alloys, so you can rest assured the gold is pure. My bet is iron particles have flaked off the mould or dies used to produced the coins and bars and become imbedded into the surface of the peice. It looks ugly... but its still pure
Technically you're refering to "oxide layer blue-gold" where you're looking through a layer of oxidised iron (rust) on the surface of the gold piece similar to the 'blue' used to protect firearms. In this case while the two metals are together (mixed), they're not bonded as a true alloy. Any other blue colours comes from gold being alloyed with varying amounts of Indium. but they're getting there...with nano-magnets http://www.newscientist.com/article...alloy-shows-power-of-magnetic-attraction.html